Ordinary thermodynamics provides reliable results when the thermodynamic fields are smooth, in the sense that there are no steep gradients and no rapid changes. In fluids and gases this is the domain of the equations of Navier-Stokes and Fourier. Extended thermodynamics becomes relevant for rapidly varying and strongly inhomogeneous processes. Thus the propagation of high­ frequency waves, and the shape of shock waves, and the regression of small-scale fluctuation are governed by extended thermodynamics. The field equations of ordinary thermodynamics are parabolic while extended thermodynamics is governed by hyperbolic systems. The main ingredients of extended thermodynamics are • field equations of balance type, • constitutive quantities depending on the present local state and • entropy as a concave function of the state variables. This set of assumptions leads to first order quasi-linear symmetric hyperbolic systems of field equations; it guarantees the well-posedness of initial value problems and finite speeds of propaga­ tion. Several tenets of irreversible thermodynamics had to be changed in subtle ways to make extended thermodynamics work. Thus, the entropy is allowed to depend on nonequilibrium vari­ ables, the entropy flux is a general constitutive quantity, and the equations for stress and heat flux contain inertial terms. New insight is therefore provided into the principle of material frame indifference. With these modifications an elegant formal structure can be set up in which, just as in classical thermostatics, all restrictive conditions--derived from the entropy principle-take the form of integrability conditions.

Rational extended thermodynamics (Springer Tracts in Natural Philosophy)

Ruggeri, Tommaso

Mueller, Ingo

Reference

Springer

Physicists firmly believe that the differential equations of nature should be hyperbolic so as to exclude action at a distance; yet the equations of irreversible thermodynamics - those of Navier-Stokes and Fourier - are parabolic. This incompatibility between the expectation of physicists and the classical laws of thermodynamics has prompted the formulation of extended thermodynamics. After describing the motifs and early evolution of this new branch of irreversible thermodynamics, the authors apply the theory to mon-atomic gases, mixtures of gases, relativistic gases, and "gases" of phonons and photons. The discussion brings into perspective the various phenomena called second sound, such as heat propagation, propagation of shear stress and concentration, and the second sound in liquid helium. The formal mathematical structure of extended thermodynamics is exposed and the theory is shown to be fully compatible with the kinetic theory of gases. The study closes with the testing of extended thermodynamics through the exploitation of its predictions for measurements of light scattering and sound propagation.

Extended Thermodynamics (Springer Tracts in Natural Philosophy)

Müller, Ingo

Computers & Technology

Classical and Relativistic Rational Extended Thermodynamics of Gases

Science & Math

Sugiyama, Masaru

Mathematics

Introduction to the Thermomechanics of Continua and Hyperbolic Systems (UNITEXT, 167)

This book is dedicated to the recent developments in RET with the aim to explore polyatomic gas, dense gas and mixture of gases in non-equilibrium. In particular we present the theory of dense gases with 14 fields, which reduces to the Navier-Stokes Fourier classical theory in the parabolic limit. Molecular RET with an arbitrary number of field-variables for polyatomic gases is also discussed and the theory is proved to be perfectly compatible with the kinetic theory in which the distribution function depends on an extra variable that takes into account a molecule’s internal degrees of freedom. Recent results on mixtures of gases with multi-temperature are presented together with a natural definition of the average temperature. The qualitative analysis and in particular, the existence of the global smooth solution and the convergence to equilibrium are also studied by taking into account the fact that the differential systems are symmetric hyperbolic. Applications to shock and sound waves are analyzed together with light scattering and heat conduction and the results are compared with experimental data.
Rational extended thermodynamics (RET) is a thermodynamic theory that is applicable to non-equilibrium phenomena. It is described by differential hyperbolic systems of balance laws with local constitutive equations. As RET has been strictly related to the kinetic theory through the closure method of moment hierarchy associated to the Boltzmann equation, the applicability range of the theory has been restricted within rarefied monatomic gases.The book represents a valuable resource for applied mathematicians, physicists and engineers, offering powerful models for potential applications like satellites reentering the atmosphere, semiconductors and nano-scale phenomena.

Rational Extended Thermodynamics beyond the Monatomic Gas

This book is dedicated to the recent developments in RET with the aim to explore polyatomic gas, dense gas and mixture of gases in non-equilibrium. In particular we present the theory of dense gases with 14 fields, which reduces to the Navier-Stokes Fourier classical theory in the parabolic limit. Molecular RET with an arbitrary number of field-variables for polyatomic gases is also discussed and the theory is proved to be perfectly compatible with the kinetic theory in which the distribution function depends on an extra variable that takes into account a molecule’s internal degrees of freedom. Recent results on mixtures of gases with multi-temperature are presented together with a natural definition of the average temperature. The qualitative analysis and in particular, the existence of the global smooth solution and the convergence to equilibrium are also studied by taking into account the fact that the differential systems are symmetric hyperbolic. Applications to shock and sound waves are analyzed together with light scattering and heat conduction and the results are compared with experimental data.Rational extended thermodynamics (RET) is a thermodynamic theory that is applicable to non-equilibrium phenomena. It is described by differential hyperbolic systems of balance laws with local constitutive equations. As RET has been strictly related to the kinetic theory through the closure method of moment hierarchy associated to the Boltzmann equation, the applicability range of the theory has been restricted within rarefied monatomic gases.The book represents a valuable resource for applied mathematicians, physicists and engineers, offering powerful models for potential applications like satellites reentering the atmosphere, semiconductors and nano-scale phenomena.

Questo testo, che giunge ora alla quarta edizione, è stato concepito principalmente per le necessità delle Scuole di Ingegneria, dove la Meccanica Razionale ha il duplice ruolo di introdurre sia alla modellizzazione fisico-matematica rigorosa che a specifiche applicazioni sviluppate poi in altri insegnamenti.&nbsp; La trattazione che qui proponiamo vuole presentare i concetti fondamentali mantenendo sempre l'attenzione rivolta alle applicazioni, a volte comuni ad altre discipline, in vista di sinergie didattiche favorite dalla presenza di corsi integrati. Abbiamo cercato di dare al libro una impostazione il più possibile coerente con questa finalità, soprattutto in alcune sezioni tradizionalmente caratterizzate da una trattazione più astratta: dai vincoli al Principio dei lavori virtuali, dal Principio di d'Alembert alla Meccanica Analitica. Abbiamo comunque mantenuto la tradizionale e, a nostro parere, irrinunciabile struttura ipotetico-deduttiva nello svolgimento delle argomentazioni, che fa ancora della Meccanica Razionale un disciplina formalmente rigorosa. Sono perciò presenti dimostrazioni anche complesse, sia pure sempre motivate alla luce del contesto applicativo nel quale si vanno a collocare. Questa edizione è frutto di un ampio lavoro di riorganizzazione e rielaborazione rispetto alla precedente e contiene, oltre a numerosi nuovi esempi, miglioramenti nella presentazione dei concetti principali e nello svolgimento delle dimostrazioni, per renderle didatticamente più efficaci.

Meccanica Razionale (La Matematica per il 3+2) (Italian Edition)

Biscari, Paolo

Saccomandi, Giuseppe

Vianello, Maurizio

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