PHOTOORGANOCATALYSIS IN ORGANIC SYNTHESIS (Catalytic Science, 18)

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PHOTOORGANOCATALYSIS IN ORGANIC SYNTHESIS (Catalytic Science, 18) image
ISBN-10:

1786346044

ISBN-13:

9781786346049

Author(s): Maurizio Fagnoni
Released: Mar 06, 2019
Format: Hardcover, 600 pages

Description:

The use of organocatalysts able to photocatalyze an organic reaction is a rapidly growing field. These photocatalyzed transformations are more environmentally sustainable with respect to the use of expensive/toxic metal-based photocatalysts.

Based on the authors' extensive experience in photogenerated intermediates, this book presents an overview on photocatalyzed organic processes having a synthetic significance, where an organic molecule functions as the photocatalyst.

After a brief introduction defining the nature and the characteristics of a photo-organocatalyst (POC), the chapters are organized according to the class of POC used, as detailed below.

  • Ketones and aldehydes
  • Quinones
  • Aromatics and cyano(hetero)aromatics
  • Sulfur heterocycles: thiapyrylium salts, thiazines, methylene blue
  • Oxygen heterocycles: pyrylium salts, eosin derivatives, fluorescein, rhodamines, rose bengal
  • Nitrogen heterocycles: porphyrins, acridinium salts, carbazoles, imides, mpg-C3N4, tetrazines, riboflavin, bodipy
Each chapter begins with a summary of the photophysical characteristics of the POCs and is followed by selected examples of synthetic applications. The last two chapters are devoted to the applications of photo-organocatalysis in polymerizations and to flow photo-organocatalysis. These in-depth explanations and practical applications make this title an essential reading for any chemistry student interested in organic (sustainable) synthesis.

Readership: Any chemistry student interested in organic (sustainable) synthesis.

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